The Mass Spectrometer


    The charge accelerator (sometimes known as an 'electron gun') used in

    this simulation has been greatly simplified. It accelerates charged objects

    by exerting an electric force upon them. The output of a real accelerator might

    consist of thousands of objects of unknown mass, charge and velocity...

    the output of this simulated accelerator is just one object, where you,

    unlike the pioneers, know it's charge and mass. The energy lost by the

    electric field becomes the kinetic energy of the charge.


    The velocity selector (also known as a Wien filter) was developed

    by Wilhelm Wien in 1898. It contains an electric field crossed with

    a magnetic field in such a way that the only objects that can make

    it through the filter in a straight line are ones that are charged,

    and have a zero net force exerted on them (...the electric force is

    equal and opposite to the magnetic force), regardless of the value of

    the object's mass or the value of the object's charge. This occurs

    when the velocity of the charged object is equal to E/B. Charged objects

    that have a velocity that isn't equal to E/B have a curved path as they pass

    through the filter.


    Any charged object that passes through the hole in the right hand barrier

    has successfully made it though the filter in a straight line, thus the

    velocity of the charged object can be confirmed.

    It now passes into a magnetic field, where the radius of the charged object's

    object's path can be detected (a charged object will 'expose' photographic paper if

    it hits the paper hard enough. The distance from the hole to the mark on the

    paper can be measured; this distance is the diameter of the circlular path

    of the charged object).


    Knowing the the radius of this path, the speed of the charged object, and the

    strength of the magnetic field, the 'charge to mass ratio', q/m, can be

    found. This was, and is, an important calculation, as it led to to the

    discovery of the charge and mass of the electron, which has had an

    enormous impact on our lives. Which sounds difficult to believe, but

    it's true :-).










For charge accelerator

   K = mv ² / 2

   W = VABq


For velocity selector

   FE = -VAB / d

   FB = Bqv

   ∑F = (FE² + FB²)½

   ∑F = ma

   ∆x = vit + ½at ²

   circumference = 2π r

   angle in radians = arc/radius

   sin θ = opposite / hypotenuse

   cos θ = adjacent / hypotenuse

   tan θ = opposite / adjacent


   The shape of a charged object's path in the selector:

        In E-field only: parabola.

        In B-field only: circular.

        In crossed E and B fields: cycloid.

        Net force is zero: straight.




For magnetic field

   FB = Bqv

   ∑F on a mass moving in a circle = mv ²/r


Close



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   K : kinetic energy of mass (joules) (J)

   W : work done on charge by electric field (joules) (J)

   m : mass of object (kilogram) (kg)

   v : velocity of mass (meters/second) (m/s)

   E : Electric field strength (volts/meter or newtons/coulomb) (V/m or N/C)

   B : Magnetic field strength (tesla) (T)

   VAB : voltage (a.k.a. electric potential difference) (volts) (V)

   VA : electric potential at A (volts) (V)

   VB : electric potential at B (volts) (V)

   q : charge (coulombs) (C)

   FE : electric force on charge (newtons) (N)

   FB : magnetic force on charge (newtons) (N)

   F : total force on charge (newtons) (N)

   a : acceleration of mass (meters/second²) (m/s²)

   r : radius (meters) (m)

   x : change in position (meters) (m)

   vi : initial velocity (meters/second) (m/s)

   ∆t : change in time (seconds) (s)



    • To be calculator and student friendly, the range of values

      chosen for this simulation have no exponents, unlike many

      of the real-world values that are used for a real

      mass spectrometer.

    • For this simulation, there are no gravitational forces.

    • In this simulation, a charged object will only pass through

      the hole in the barrier if its path has been a continuous

      straight line from the accelerator to the barrier.

    • There is no motion in the z direction.

    • Assume that there are no edge effects.

    • This simulation is not to scale.

ResetReplaySlowStartPause


charge accelerator

gun electric field

gun voltage

gun separation

gun length

exit velocity

selector electric field

selector voltage

selector separation


selector length


selector magnetic field

b2 value

charge

mass


MassSpectrometerSim

velocity selector

velocity selector removed

magnetic field

magnetic field removed

charge and mass

Display...

charge accelerator








velocity selector











magnetic field






charge and mass




information